The Starzach site in Southern Germany: a site with naturally occurring CO<Subscript>2</Subscript> emissions recovering from century-long gas mining as a natural analog for a leaking CCS reservoir     

Alexander Lübben  Carsten Leven 《Environmental Earth Sciences》2018,77(8):316

In this paper, we present the Starzach site, a region featuring numerous natural CO₂ emission spots, such as mofettes, that reappeared after a longer period of extensive industrial CO₂ mining. We discuss the results of a detailed literature study on the geological setting and the activities related to the gas mining in combination with own measurements to introduce the site as an example on how gas leakage from an insecure CCS reservoir could manifest at the surface. The site is in particular interesting for such investigations as the CO₂ emissions started to replenish after the end of the CO₂ mining and offers the unique possibility to investigate an increase in degassing activity as it might be expected for an active CCS site where leakage is suspected. Based on the geological setting and soil, gas emission, and isotope investigations, we further discuss the source of the CO₂ emission and the gas ascent to the ground surface via deep-reaching faults, latter being so far excluded by previous work. The combination of our extensive literature review and recent field investigations allowed us to draw new geological conclusions for the site that were under discussion for a long time and to give insight into the site’s potential for CCS-related analog studies in the future.  相似文献   

Hydrogeochemical investigation of geothermal springs in Erzurum,East Anatolia (Turkey)     

Mine Alacali 《Environmental Earth Sciences》2018,77(24):802

Geothermal water sources located within The Erzurum province were identified and hot water samples were taken from four different geothermal areas. The results of in situ and hydrogeochemical analyses of these hot water samples were interpreted and the properties of hot water, water–rock associations, estimated reservoir temperature and hot water usage areas were determined. The temperatures of the samples collected from the study area vary between 26.2 and 57.7 °C, while pH values change from 6.09 to 7.33, EC values obtained from in situ measurements are between 1829 and 9480 µS/cm and Eh values are (??190) to (26.3) mV. Total dissolved solids of the hot waters have a range from 838.7 to 3914.1 mg/l. The maximum estimated reservoir temperature is calculated as 250 °C by applying chemical geothermometers. However, considering the actual temperatures of Pasinler, Köprüköy, Horasan and Il?ca thermal waters and wells, the most reliable temperature range depending on the applied geothermometers’ results indicate minimum and maximum reservoir temperatures 85–158.9 °C, respectively, taking in account the errors. According to the isotope analysis, the waters circulating within the geothermal system are of meteoric origin and modern waters. In addition, two samples taken from clayey levels observed in the field were analyzed and the mineralogy of the clays was evaluated.  相似文献   

Characterizing groundwater recharge using oxygen and hydrogen isotopes: a case study in a temperate forested region,South Korea     

Mukesh Kumar Gautam  Kwang-Sik Lee  Byeong-Yeol Song 《Environmental Earth Sciences》2018,77(3):110

In the cool temperate region of South Korea, oxygen and hydrogen isotopes of groundwater, lake water, and precipitation were studied to determine the season of groundwater recharge. All the groundwater samples, irrespective of season, on δ¹⁸O–δ²H scale plotted along the summer precipitation, suggesting summer precipitation largely modulates recharge. The deuterium excess values of groundwater (d-excess) show clear seasonal difference, higher in winter (> 18‰) and lower in summer (< 10‰). And its resemblance to the summer precipitation d-excess value further suggests dominant role of summer precipitation in groundwater recharge. Based on the mass balance equation, with end-member d-excess values of seasonal precipitation and groundwater as input variables, groundwater is composed of 66% summer and 34% winter precipitation. Despite the study area being heavily forested, summer rainfall contribution higher than winter suggests that evapotranspiration effect is minimal in the region; may be due to thin sand–gravel-based porous soil overlying highly weathered granitic rock system.  相似文献   

Heavy metals status,transport mechanisms,sources, and factors affecting their mobility in Chinese agricultural soils   总被引：3，自引：0，他引：3  

Feng Jing  Xiaomin Chen  Zhijiang Yang  Bilin Guo 《Environmental Earth Sciences》2018,77(3):104

Heavy metals are the focus of much interest because of their environmental persistence, toxicity, and mobility in soils. Some of the Chinese soils have been contaminated with heavy metals due to expansion of mining industries, pesticides usage, and other anthropological activities, which made the agro-ecosystem to become contaminated. The objective of this review is to illuminate the current pollution status, sources of heavy metals, transport mechanisms, and the factors affecting their mobility in Chinese soils. The additional studies in the future will present on source identification and the heavy metal transport characteristics in soil.  相似文献   

Quantifying land use influences on event-based flow frequency,timing, magnitude,and rate of change in an urbanizing watershed of the central USA     

Sean J. Zeiger  Jason A. Hubbart 《Environmental Earth Sciences》2018,77(3):107

There is a need for research that advances understanding of flow alterations in contemporary watersheds where natural and anthropogenic interactions can confound mitigation efforts. Event-based flow frequency, timing, magnitude, and rate of change were quantified at five-site nested gauging sites in a representative mixed-land-use watershed of the central USA. Statistically independent storms were paired by site (n = 111 × 5 sites) to test for significant differences in event-based rainfall and flow response variables (n = 17) between gauging sites. Increased frequency of small peak flow events (i.e., 64 more events less than 4.0 m³ s^?1) was observed at the rural–urban interface of the watershed. Differences in flow response were apparent during drier periods when small rainfall events resulted in increased flow response at urban sites in the lower reaches. Relationships between rainfall and peak flow were stronger with decreased pasture/crop land use and increased urban land use by approximately 20%. Event-based total rainfall explained 40–68% of the variance in peak flow (p < 0.001). Coefficients of determination (r²) were negatively correlated with pasture/crop land use (r² = 0.92; p = 0.007; n = 5) and positively correlated with urban land use (r² = 0.90; p = 0.008; n = 5). Significant differences in flow metrics were observed between rural and urban sites (p < 0.05; n = 111) that were not explained by differences in rainfall variables and drainage area. An urban influence on flow timing was observed using median time lag to peak centroid and time of maximum precipitation to peak flow. Results highlight the need to establish manageable flow targets in rapidly urbanizing mixed-land-use watersheds.  相似文献   

Effects of historical and projected land use/cover change on runoff and sediment yield in the Netravati river basin,Western Ghats,India     

Rakesh Kumar Sinha  T. I. Eldho 《Environmental Earth Sciences》2018,77(3):111

In this study, the effects of changes in historical and projected land use land cover (LULC) on monthly streamflow and sediment yield for the Netravati river basin in the Western Ghats of India are explored using land use maps from six time periods (1972, 1979, 1991, 2000, 2012, and 2030) and the soil and water assessment tool (SWAT). The LULC for 2030 is projected using the land change modeller with the assumption of normal growth. The sensitivity analysis, model calibration, and validation indicated that the SWAT model could reasonably simulate streamflow and sediment yield in the river basin. The results showed that the spatial extent of the LULC classes of urban (1.80–9.96%), agriculture (31.38–55.75%), and water bodies (1.48–2.66%) increased, whereas that of forest (53.04–27.03%), grassland (11.17–4.41%), and bare land (1.09–0.16%) decreased from 1972 to 2030. The streamflow increased steadily (7.88%) with changes in LULC, whereas the average annual sediment yield decreased (0.028%) between 1972 and 1991 and increased later (0.029%) until 2012. However, it may increase by 0.43% from 2012 to 2030. The results indicate that LULC changes in urbanization and agricultural intensification have contributed to the increase in runoff, amounting to 428.65 and 58.67 mm, respectively, and sediment yield, amounting to 348 and 43 ton/km², respectively, in the catchment area from 1972 to 2030. The proposed methodology can be applied to other river basins for which temporal digital LULC maps are available for better water resource management plans.  相似文献   

The Red Sea depositional architecture: insights from 3D modeling     

Khalid A. Almalki  Syed A. Mahmud  Hisham I. Hashem  Oumar A. Loni 《Arabian Journal of Geosciences》2018,11(11):277

More than half a century of geological and exploration studies have taken place in the Red Sea area, and still very limited information is available to the geological community in regard to the lithological distribution and the stratigraphic architecture. In this study, extensive well data was used to build the first lithologic and stratigraphic 3D models of the entire Red Sea to better understand the lithological distribution. The potential models have been constrained by bathymetric and geophysical data. Studied data demonstrate that up to 5 km of sediments were deposited in the Red Sea. It is mainly comprised of limestones, evaporites, and shales. Our models show that the evaporite body represents more than 70% of the Red Sea succession. In particular, the evaporite succession seems to be well developed in the southern region. Salt dome features are present and developed close to the margins. The models suggest that domal formation did not enable thick carbonate accumulation in some parts of the basin but the carbonate generally follows the evaporite trend. The models help to identify the main controls leading to salt diapir by highlighting the distribution of this body and the geometry of geological structures. Syn-rift faulting and rifting has been one of the most prominent structural features. Complex interplay of tectono-stratigraphic events played a significant role in shaping the stratigraphic evolution of the Red Sea basin with multiple evolution phases of paleoenvironment and paleogeographic were recognized based on the models. Our synthesis and interpretation support that moderately deep marine conditions dominated in the Miocene, whereas shallow seas dominated the whole basin during the Plio-Pleistocene period as a result of episodic marine invasion. However, lacustrine environment may have prevailed at the Oligocene time in isolated half grabens.  相似文献   

Effect of climate change on water resources in the Yuanshui River Basin: a SWAT model assessment     

Yingdong Yu  Jiahong Liu  Zhiyong Yang  Yongqiang Cao  Jing Chang  Chao Mei 《Arabian Journal of Geosciences》2018,11(11):270

The Yuanshui River Basin is one of the most important river basins ensuring food production and livelihoods in the Hunan and Guizhou Provinces of China. Based on digital elevation model, land use, soil, and meteorological data, the soil and water assessment tool was used to analyze the response of water resources in the basin to climate change. Specifically, the monthly runoff from the Yuanshui River Basin was simulated. Runoff measurements from the 1961–1990 series were used to calibrate model parameters, and measurements from the 1991–2010 series were used for model validation. The Nash–Sutcliffe efficiency coefficient, correlation coefficient, and water balance error were used to evaluate the simulation results; the values obtained for these parameters were 0.925, 0.929, and 2.0%, respectively, indicating that the established model can be applied successfully to runoff simulations. To evaluate the effects of climate change and human activities on runoff, 24 different climate scenarios were modeled. By comparing the model simulation results with the baseline scenario, the effects of climate change were analyzed by year, during the dry season, and during extremely dry conditions. The results showed that runoff decreased with increasing air temperature and decreasing precipitation, and that the effects of rainfall on runoff were greater than those of air temperature. Under the same baseline conditions, the effects of climate change on runoff were most pronounced during extremely dry months.  相似文献   

Hydrothermal alteration and evolution of Zr-Th-U-REE mineralization in the microgranite of Wadi Ras Abda,North Eastern Desert,Egypt     

Amr Abdel Aty Abdel Hamid  Hassan Ismail El Sundoly  Ahmed Ali Abu Steet 《Arabian Journal of Geosciences》2018,11(11):273

Ras Abda plutonic suite, North Eastern Desert of Egypt, consists predominantly of Neoproterozoic calc-alkaline older granites. Minor exposures of pink microgranite are occurring along Wadi Ras Abda within the older granites. Previous studies on this area demonstrated that the microgranite is altered in some parts and contains anomalous concentrations of rare metal elements (Zr, Th, and U). These altered and mineralized zones are re-assessed using field observations, chemical analysis, and by the application of various transmitted light and electron microscopic techniques. The rare metals exist as mineral segregation grew freely into open cavities of the microgranite and concordant with the NNE strike-slip fault movement. The mineralized zones contain an assemblage of secondary magnetite, zircon, uranothorite, columbite-(Mn), fergusonite-(Y), and allanite-(Ce). The extreme abundance of zircon in the mineralized zone, along with other evidence, indicates a hydrothermal origin of this zircon together with associated rare metals. The geochemical investigation and mass balance calculations revealed extreme enrichment of Zr, Th, U, Y, Nb, Ta, and REE. Post-magmatic hydrothermal alterations resulted in such pronounced chemical and mineralogical heterogeneity. The hydrothermal fluids are thought to be oxidizing, alkaline and of medium temperature (>?250 °C). The average contents of the elements Zr (1606 ppm), Th (1639 ppm), U (306 ppm), Nb (955 ppm), and REE (1710 ppm) in the mineralized microgranite reach sub-economic levels and could be a potential source of these elements.  相似文献   

Hypsometric analysis of the micro-watersheds with different management practices located on Shivalik foothills     

Sushma Walia  Sarbjit Singh  Dikesh Chandra Loshali  Richa Babbar 《Arabian Journal of Geosciences》2018,11(11):276

In this paper, the hypsometric curves and integrals of four neighboring micro-watersheds draining into Patiala-Ki-Rao stream which is situated in the Shivalik foothills of district SAS Nagar in the Punjab state (India) has been presented to access and compare the erosion regimes under different management practices. Area-elevation ratio method has been used to compute hypsometric curve and integral values for each micro-watershed through ArcGIS 10.3 and Microsoft Excel. The 9-year data of runoff and sediment yield for all these micro-watersheds under different management practices has been analyzed for their effect on land cover and soil quality. Thus, the results of present study are very useful for comparing, planning, implementing, and controlling soil erosion in similar watersheds.  相似文献